1.2. Threshold value.

Odour threshold is the lowest concentration of a compound that can still be directly recognized by its odour. The threshold concentrations allow comparison of the intensity of odourous substances. Some examples are given in Table 1. These examples illustrate that great differences exist between individual aroma compounds, with an odour potential range of several orders of magnitude.

Odour threshold values in water of some aroma compounds at 20 ºC.
CompoundThreshold
value / mgL-1
Compound Threshold
value / mgL-1
Pyrazine300Ethylbutyrate0.001
Ethanol100(+)-Nootkatone0.001
Maltol  35(-)-Nootkatone1.0
Hexanol    0.72-Methylbutyric acid ethyl ester0.0001
Butyric acid    0.24-Hydroxy-2,5-dimethyl-3(2H9-furanone0.00004
Vanillin    0.024-Methoxy-2,5-dimethyl-3(2H9-furanone0.00003
Limonene    0.01Methylmercaptan0.00002
Linalool    0.006b-Damascone0.000009
Hexanal    0.0045b-Ionone0.000007
2-Phenylethanal    0.0042-Isobutyl-3-methylpyrazine0.000002
a-Ionone    0.0041-p-enthen-8-thiol0.00000002
2- Methylpropanal    0.001  
Adapted from Belitz and Grosch (1987)

Some discrepancies can be found in literature for the threshold concentrations. These discrepancies are due to the fact that the threshold concentrations for aroma compounds are dependent on their vapour pressure, which is affected by both temperature and medium. The values are also influenced by the assay procedure and/or the performance of the sensory panel.


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